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Entropy production analysis of swirling diffusion combustion processes

Deodat MAKHANLALL, Linhua LIU,

《能源前沿（英文）》 2010年第4卷第3期页码 326-332 doi: 10.1007/s11708-009-0058-1

摘要： A critical factor in the design of combustion systems for optimum fuel economy and emission performance lies in adequately predicting thermodynamic irreversibilities associated with transport and chemical processes. The objective of this study is to map these irreversibilities in terms of entropy production for methane combustion. The numerical solution of the combustion process is conducted with the help of a Fluent 6.1.22 computer code, and the volumetric entropy production rate due to chemical reaction, viscous dissipation, and mass and heat transfer are calculated as post-processed quantities with the computed data of the reaction rates, fluid velocity, temperature and radiative intensity. This paper shows that radiative heat transfer, which is an important source of entropy production, cannot be omitted for combustion systems. The study is extended by conducting a parametric investigation to include the effects of wall emissivity, optical thickness, swirl number, and Boltzmann number on entropy production. Global entropy production rates decrease with the increase in swirl velocity, wall emissivity and optical thickness. Introducing swirling air into the combustion system and operations with the appropriate Boltzmann number reduces the irreversibility affected regions and improves energy utilization efficiency.

关键词： entropy-based design radiation transfer swirl magnussen combustion-model

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Combustion analysis of a hydrogen-diesel fuel operated DI diesel engine with exhaust gas recirculation

M. LOGANATHAN, A. VELMURUGAN, TOM PAGE, E. JAMES GUNASEKARAN, P. TAMILARASAN

《能源前沿（英文）》 2017年第11卷第4期页码 568-574 doi: 10.1007/s11708-017-0461-y

摘要： The rapid depletion of fossil fuel and growing demand necessitates researchers to find alternative fuels which are clean and sustainable. The need for finding renewable, low cost and environmentally friendly fuel resources can never be understated. An efficient method of generation and storage of hydrogen will enable automotive manufacturers to introduce hydrogen fuelled engine in the market. In this paper, a conventional DI diesel engine was modified to operate as gas engine. The intake manifold of the engine was supplied with hydrogen along with recirculated exhaust gas and air. The injection rates of hydrogen were maintained at three levels with 2 L/min, 4 L/min, 6 L/min and 8 L/min and 10 L/min with an injection pressure of 2 bar. Many of the combustion parameters like heat release rate (HRR), ignition delay, combustion duration, rate of pressure rise (ROPR), cumulative heat release rate (CHR), and cyclic pressure fluctuations were measured. The HRR peak pressure decreased with the increase in EGR rate, while combustion duration increased with the EGR rate. The cyclic pressure variation also increased with the increase in EGR rate.

关键词： hydrogen exhaust gas recirculation (EGR) diesel combustion heat release rate (HRR) combustion duration

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Thermogravimetric kinetic analysis of

SUKARNI,SUDJITO,Nurkholis HAMIDI,Uun YANUHAR,I.N.G. WARDANA

《能源前沿（英文）》 2015年第9卷第2期页码 125-133 doi: 10.1007/s11708-015-0346-x

摘要： The thermal behavior of combustion in air atmosphere were investigated by performing experiments on STA PT1600 Thermal Analyzer at heating rates of 10°C/min, 40°C/min and 70°C/min and range of temperatures from room temperature to 1200°C. The kinetic parameters were evaluated by using Kissinger and Ozawa methods. The result showed that combustion occurred in five stages. Started with initial devolatilization, the main thermal decomposition and combustion process, transition stage, the combustion of char and the last stage was the slow burning reaction of residual char. In line with increasing heating rate, the mass loss rate increased as well, but it delayed the thermal decomposition processes toward higher temperatures. The average activation energy at the main thermal decomposition stage and the stage of char combustion were approximately 251 kJ/mol and 178 kJ/mol, respectively.

关键词： Nannochloropsis oculata combustion kinetic parameters air atmosphere thermogravimetric

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Modeling and simulation analysis on parallel hybrid air-fuel vehicle

Pinglu CHEN, Xiaoli YU, Xianghong NIE, Yidong FANG

《能源前沿（英文）》 2010年第4卷第4期页码 553-559 doi: 10.1007/s11708-010-0008-y

摘要： Based on the vehicle simulation software ADVISOR, the model of a parallel air-fuel hybrid vehicle was established, and the modeling of an air powered engine (APE), heat exchanger, braking air tank and control strategy were discussed in detail. Using the vehicle model, a hybrid vehicle refitted from a traditional diesel car was analyzed. The results show that for the New European Driving Cycle (NEDC), the Urban Dynamometer Driving Schedule (UDDS) and the Highway Fuel Economy Test (HWFET) driving cycle, the total reductions in fossil fuel consumption of the hybrid vehicle were 48.29%, 48.51% and 22.07%, respectively, and the emissions could be decreased greatly compared with the traditional diesel car, while the compressed air consumptions of the hybrid vehicle were 97.366, 85.292 and 56.358 kg/100 km, respectively. Using the diesel equivalent as the indicator of fuel economy, the hybrid vehicle could improve the fuel economy by 14.71% and 16.75% for the NEDC and the UDDS driving cycles and decrease by 5.04% for the HWFET driving cycle compared with the traditional car. The simulation model and analysis in this paper could act as the theoretical basis and research platform in optimizing the key components and control strategy of hybrid air-fuel vehicles.

关键词： air powered engine hybrid vehicle internal combustion engine simulation

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Combustion characteristics and kinetics of bio-oil

Ruixia ZHANG, Zhaoping ZHONG, Yaji HUANG

《化学科学与工程前沿（英文）》 2009年第3卷第2期页码 119-124 doi: 10.1007/s11705-009-0068-x

摘要： The combustion characteristics of bio-oils derived from rice husk and corn were studied by thermogravimetry analysis. According to the thermogravimetry (TG), differential thermogravimetry (DTG) and differential thermal analysis (DTA) curves of bio-oils in air and nitrogen atmosphere, we analyzed the combustion characteristics of different kinds of bio-oils in different atmospheres and worked out the combustion kinetics parameters of the bio-oil, providing reliable base data for the burning of bio-oil. The thermogravimetry indicated that the combustion process of bio-oil was divided into three stages. At the same time, the combustion process can be described by different order reaction models, and with the method of Coats-Redfern, the activation energy and frequency factor of different kinds of bio-oils were obtained.

关键词： bio-oil combustion characteristics combustion kinetics

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Thermogravimetric coupled with Fourier transform infrared analysis study on thermal treatment of monopotassium

Yuheng FENG, Xuguang JIANG, Yong CHI, Xiaodong LI, Hongmei ZHU

《环境科学与工程前沿（英文）》 2011年第5卷第2期页码 186-192 doi: 10.1007/s11783-011-0322-6

摘要： In China, safe disposal of hazardous waste is more and more a necessity, urged by rapid economic development. The pyrolysis and combustion characteristics of a residue from producing monopotassium phosphate (monopotassium phosphate residue), considered as a hazardous waste, were studied using a thermogravimetric, coupled with Fourier transform infrared analyzer (TG-FTIR). Both pyrolysis and combustion runs can be subdivided into three stages: drying, thermal decomposition, and final devolatilization. The average weight loss rate during fast thermal decomposition stage in pyrolysis is higher than combustion. Acetic acid, methane, pentane, (acetyl) cyclopropane, 2,4,6-trichlorophenol, CO, and CO were distinguished in the pyrolysis process, while CO was the dominant combustion product.

关键词： hazardous waste combustion pyrolysis thermogravimetric coupled with Fourier transform infrared analysis (TG-FTIR) monopotassium phosphate residue

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Numerical simulation of laminar premixed combustion in a porous burner

ZHAO Pinghui, CHEN Yiliang, LIU Minghou, DING Min, ZHANG Genxuan

《能源前沿（英文）》 2007年第1卷第2期页码 233-238 doi: 10.1007/s11708-007-0032-8

摘要： Premixed combustion in porous media differs substantially from combustion in free space. The interphase heat transfer between a gas mixture and a porous medium becomes dominant in the premixed combustion process. In this paper, the premixed combustion of CH

关键词： interphase mixture dominant Premixed combustion premixed combustion

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Study on combustion characteristics of blended coals

LI Yonghua, WANG Chunbo, CHEN Hongwei

《能源前沿（英文）》 2007年第1卷第1期页码 96-100 doi: 10.1007/s11708-007-0010-1

摘要： Power plants in China have to burn blended coal instead of one specific coal for a variety of reasons. So it is of great necessity to investigate the combustion of blended coals. Using a test rig with a capacity of 640 MJ/h with an absolute milling system and flue gas online analysis system, characteristics such as burnout, slag, and pollution of some blended coals were investigated. The ratio of coke and slag as a method of distinguishing coal slagging characteristic was introduced. The results show that the blending of coal has some effect on NO but there is no obvious rule. SO emission can be reduced by blending low sulfur coal.

关键词： combustion capacity variety blended burnout

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Recent progress in electric-field assisted combustion: a brief review

《能源前沿（英文）》 2022年第16卷第6期页码 883-899 doi: 10.1007/s11708-021-0770-z

摘要： The control of combustion is a hot and classical topic. Among the combustion technologies, electric-field assisted combustion is an advanced techno-logy that enjoys major advantages such as fast response and low power consumption compared with thermal power. However, its fundamental principle and impacts on the flames are complicated due to the coupling between physics, chemistry, and electromagnetics. In the last two decades, tremendous efforts have been made to understand electric-field assisted combustion. New observations have been reported based on different combustion systems and improved diagnostics. The main impacts, including flame stabilization, emission reduction, and flame propagation, have been revealed by both simulative and experimental studies. These findings significantly facilitate the application of electric-field assisted combustion. This brief review is intended to provide a comprehensive overview of the recent progress of this combustion technology and further point out research opportunities worth investigation.

关键词： electric field combustion flame stabilization emission reduction flame propagation

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Catalytic combustion of volatile organic compounds using perovskite oxides catalysts—a review

《化学科学与工程前沿（英文）》 2023年第17卷第11期页码 1649-1676 doi: 10.1007/s11705-023-2324-x

摘要： With the rapid development of industry, volatile organic compounds (VOCs) are gaining attention as a class of pollutants that need to be eliminated due to their adverse effects on the environment and human health. Catalytic combustion is the most popular technology used for the removal of VOCs as it can be adapted to different organic emissions under mild conditions. This review first introduces the hazards of VOCs, their treatment technologies, and summarizes the treatment mechanism issues. Next, the characteristics and catalytic performance of perovskite oxides as catalysts for VOC removal are expounded, with a special focus on lattice distortions and surface defects caused by metal doping and surface modifications, and on the treatment of different VOCs. The challenges and the prospects regarding the design of perovskite oxides catalysts for the catalytic combustion of VOCs are also discussed. This review provides a reference base for improving the performance of perovskite catalysts to treat VOCs.

关键词： perovskite oxides volatile organic compounds catalytic combustion reaction mechanism

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Identifying combustion intermediates in premixed MTBE/gasoline/oxygen flame probed via synchrotron radiation

YAO Chunde, LI Jing, LI Qi, JI Qing, HUANG Chaoqun, WEI Lixia, WANG Jing, TIAN Zhenyu, LI Yuyang, QI Fei

《能源前沿（英文）》 2007年第1卷第1期页码 79-84 doi: 10.1007/s11708-007-0007-9

摘要： Molecular-beam sampling mass spectrometry (MBMS) combined with tunable synchrotron radiation photoionization technique offers obvious advantages for the study of flame chemistry over other techniques because of the precision measurement of the combustion intermediates and products in flame. In this paper, the results to identify combustion intermediates in low-pressure premixed gasoline/oxygen flame with the synchrotron radiation were reported. Based on the results obtained, the formation process of five products and the difference between gasoline/oxygen and MTBE/gasoline/oxygen flame were emphatically analyzed. The results achieved provide data basis for the analysis of intermediates and radicals in flame, and are helpful to establish the kinetic modeling of gasoline/oxygen and MTBE/gasoline/oxygen flames.

关键词： synchrotron photoionization technique chemistry analysis difference

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Impact of oxygen enriched combustion on the performance of a single cylinder diesel engine

K. RAJKUMAR, P. GOVINDARAJAN

《能源前沿（英文）》 2011年第5卷第4期页码 398-403 doi: 10.1007/s11708-011-0157-7

摘要： In the present experiment, a computerized single cylinder diesel engine with a data acquisition system was used to study the effects of oxygen enriched combustion technology (OECT) on the performance characteristics. The use of different levels of oxygen-enriched air was compared with respect to percentage load. Increasing the oxygen content in the air leads to faster burn rates and increases the combustibility at the same stoichiometry (oxygen-to-fuel ratio). These effects have the potential to increase the thermal efficiency and specific power output of a diesel engine. The power increases considerably with oxygen enrichment. In addition, oxygen enrichment can also be considered as a way to reduce the sudden loss in power output when the engine operates in a high load condition. Assessed high combustion temperature from the oxygen enriched combustion leads to high combustion efficiency. OECT reduces the volume of flue gases and reduces the effects of greenhouse effects. Engine tests were conducted in the above said engine for different loads and the following performance characteristics like brake power (BP), specific fuel consumption (SFC), mean effective pressure, brake thermal efficiency, mechanical efficiency, and exhaust gas temperature were studied. The objective of this paper is to address, in a systematic way, the key technical issues associated with applying OECT to single cylinder diesel engines.

关键词： oxygen enriched combustion exhaust gas temperature brake power (BP) specific fuel consumption (SFC)

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Effect of Fe on NO release during char combustion in air and O

Ying GU, Xiaowei LIU, Bo ZHAO, Minghou XU

《能源前沿（英文）》 2012年第6卷第2期页码 200-206 doi: 10.1007/s11708-012-0181-2

摘要： The chemistry of char was probed by studying nitrogen release under the reactions with air and oxy-fuel combustion. The experiments were conducted in a drop tube furnace and a fixed bed flow reactor. NO was observed during those experiments. The results show that the particle size of char generated at 1073 K in CO is larger than that in N . However, at 1573 K, it is smaller in CO atmosphere due to particle breaking by gasification of char and CO . The Fe addition increases the NO conversion ratio, and the effect of Fe rises steeply with the process going until it becomes stable in the end. The results also indicate that the release of NO increases more significantly with the Fe addition in oxy-fuel environment.

关键词： NO Fe char combustion CO₂

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Influence of temperature on cam-tappet lubrication in an internal combustion engine

CHANG Qiuying, YANG Peiran, WANG Jing, CHEN Quanshi

《机械工程前沿（英文）》 2007年第2卷第4期页码 489-492 doi: 10.1007/s11465-007-0085-8

摘要： The transient thermo-elastohydrodynamic (TEHL) lubrication simulation and isothermal elastohydrodynamic (EHL) simulation were performed on the exhausting cam-tappet friction pair of an internal combustion engine. Although by employing the two models the center pressure, the thickness of the lubricant film and friction coefficient obtained were similar in the changing trend during a rotating cycle, the parameters make a great difference, especially for the thickness of the lubricant film; the TEHL was four times thicker than the EHL. These results show that the temperature should not be neglected in the study of the lubrication of cam-tappet pairs.

关键词： coefficient combustion isothermal elastohydrodynamic temperature thickness

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Numerical simulation of charge stratifications to improve combustion and NO formation of lean-burn SI

Zhijun PENG ,

《能源前沿（英文）》 2009年第3卷第3期页码 353-358 doi: 10.1007/s11708-009-0035-8

摘要： The influences of charge stratification on spark ignition (SI) engine combustion and NO emission were analyzed using a phenomenological model. The mixture in the cylinder was divided spherically into three parts: a central core with a stoichiometric air-fuel charge, a dilution region without any combustible charge, and a mixing region lying between the core and the dilution region. Three mixture stratification parameters such as the extent of dilution in the mixing region, the extent of combustible charge in the mixing region, and the gradient of stratification in the mixing region were investigated. The results indicate that the extent of combustible charge in the mixing region could reduce in-cylinder NO formation significantly, compared with the extent of dilution in the mixing region. As long as the degree of dilution in the mixing region is within the dilution limit of the combustible charge, the gradient of dilution has little effect on combustion and NO formation.

关键词： charge stratification SI engine lean-burn combustion NO emission